Seminar : March 10th
New dimensions of spectroscopy; no fear of wild molecules
10:30 Vancouver – 11:30 Edmonton – 12:30 Winnipeg – 13:30 Montreal – 14:30 Halifax
Keynote
Jennifer P. Ogilvie
Physics Department at the University of Michigan, Ann Arbor, Michigan, United States
Multispectral and Spatially-resolved Multidimensional Spectroscopy
Abstract: There is currently a revolution in optical spectroscopies to develop multidimensional approaches that provide sensitive probes of structure and dynamics in condensed-phase systems spanning decades in space and time. I will discuss our development of a multispectral multidimensional spectrometer enabling measurements from the ultraviolet, visible and mid-infrared as well as combination spectroscopies. I will illustrate some of the capabilities of the instrument through our efforts to probe the electronic structure and charge separation mechanisms in natural and artificial light-harvesting systems. I will also discuss our development of phase-modulation-based spatially-resolved multidimensional spectroscopy, enabling in vivomeasurements on biological systems and will discuss the promise of this new approach for imaging of biological and material systems.
Bio: Jennifer P. Ogilvie is a Professor in the Physics Department at the University of Michigan, Ann Arbor. She received her B.Sc. from the University of Waterloo, her M.Sc. degree from Simon Fraser University, Canada, and her Ph.D. in Physics from the University of Toronto, Canada. She was a Postdoctoral Fellow in the Laboratory for Optics and Biosciences at the Ecole Polytechnique. Ogilvie’s group develops multidimensional spectroscopy and imaging methods and applies them to studies of ultrafast energy transfer and charge separation in natural and artificial photosynthetic systems. She is a Sloan Fellow and a Fellow of the Optical Society of America.
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Invited
Vincent Wanie
Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Hamburg, Germany
Few-optical-cycle UV pulse generation and applications in molecular science
Abstract: Ultraviolet (UV)radiation being an essential element in a wide range of scientific areas, advances of UV light sources promise to have an impact not only for engineering new technologies but also for fundamental research.
In molecular science, well-established spectroscopic methods have allowed to study in real-time the evolution of photo-induced chemical reactions with few-femtosecond (fs) and even sub-fs time resolution [1]. However, the investigation of UV-induced phenomena at such timescales is still in its infancy due to the technological challenges for the production and manipulation of ultrabroadband, few-fs UV pulses [2].
In this presentation, thecurrently available state-of-the-art technologies delivering few-fs UV pulses will first be discussed, together with their advantages and limitations.I will notably present the recent developments following our generation of sub-2-fs, 150 nJ UV pulses [3],obtained by third-harmonic generationof 800 nm, 5-fs pulses in argon gas.The light source is embedded into an all-vacuum beamline for dispersion-free spectroscopic applications, where UV pulses can be synchronized to either few-cyclenear-infrared or attosecond XUV (15-50 eV) pulses for time-resolved measurements.
Finally, the investigation of UV-induced dynamics in a few molecular targets will be presented, using the UV-pump/near-infrared-probe scheme. The results show that the unprecedented temporal resolution provided by our experimental setup allows us to resolve ultrafast phenomena within few tens of fs such as chiroptical switching effects in chiral molecules and non-adiabatic dynamics in halogenated hydrocarbons.Our work marks an important step forward in the field of molecular UV spectroscopy, while the application of our compact UV light source can be further extended to the study of a number of materials for photonic applications.
- F.Calegari et al., “Advances in attosecond science,” J. Phys. B: At. Mol. Opt. Phys 49, 062001 (2016).
2. V. Wanie et al., “Advances of ultraviolet light sources: towards femtosecond pulses in the few-cycle regime,” in Emerging Laser Technologies for High-Power and Ultrafast Science(IOP Publishing, 2021).
3. M.Galli, V. Wanie et al., “Generation of deep ultraviolet sub-2-fs pulses,” Optics Letters 44, 1308-1311 (2019).
Bio:
Since 07/2021: Senior Scientist (tenured) in the Attosecond Science group of the DESY Photon Science Division, Hamburg, Germany.
01/2021 – 06/2021: Postdoctoral researcher in the Attosecond Science group of the DESY Photon Science Division, Hamburg, Germany.
2015 – 2020: PhD in Energy and Materials Sciences, INRS-ÉMT, Canada
- Funded by the Vanier Canada Graduate Scholarship.
- Thesis title: Probing and controlling few-femtosecond dynamics with ultrashort laser pulses: from gases to solids.
2014 – 2015: Master Degree in Energy and Materials Sciences – Fast-track to PhD, INRS-ÉMT, Canada.
2010 – 2013: B. Sc.in Chemistry, Université de Sherbrooke, Canada.